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Studies on hydrogen bonds. Part 1
A K CHANDRA, S BASU
Published in -
1960
Volume: 56
   
Pages: 632 - 637
Abstract
The equilibrium constants of the hydrogen-bonded complexes of pyridazine, diethyl nitrosoamine and benzophenone with five different alcohols have been estimated from the n→π* blue shift and the optical density measurements at the peak. The equilibrium constants have been found to increase in the order primary >secondary>tertiary. The role of various complicating factors in the oxygenated systems has been discussed. The free-energy change has been found to be in the range of 0.1-0.8 kcal/mole.
About the journal
JournalTransactions of the Faraday Society
Publisher-
ISSN0014-7672