Positron annihilation lifetime (PAL) measurements on well-characterized pellets of Bi-2212, (Bi,Pb)-2212 and (Bi,Pb)-2223 superconductors indicate the presence of a very long (around 1500 ps) third lifetime. This τ3 is attributed to positronium formation in voids even in these conducting oxides and subsequent o-Ps to p-Ps conversion. Ignoring τ3 in the fit leads to altered values of τ1 and τ2. © 1995.