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Oxalato‐ and Malonato‐complexes of trivalent metals. II. Stabilities of Tris‐oxalato Complexes of Iron, Chromium, Aluminium, and Gallium
N K DUTT, B SUR
Published in -
1957
Volume: 293
   
Issue: 43528
Pages: 195 - 203
Abstract
The stabilities of tris‐oxalato complexes of trivalent metals like Fe, Cr, Al, Ga have been studied. These compounds have been found to decompose in steps by interaction with acids. The stepwise instability constants and also the overall instability constants of the reactions MOx3‴ → MOx′2 + Ox″, MOx′2 → MOx+ + Ox″, MOx+ → M3+ + Ox″ and MOx3‴ → M3+ + 3 Ox″ have been measured. Copyright © 1957 Verlag GmbH & Co. KGaA, Weinheim
About the journal
JournalZAAC ‐ Journal of Inorganic and General Chemistry
Publisher-
ISSN0044-2313