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Nitrosyl Rhenium Complexes: Iodonitrosyl derivatives
T K JANA, S RAKSHIT, P BANDYOPADHYAY, B K SEN
Published in -
1981
Volume: 477
   
Issue: 6
Pages: 229 - 234
Abstract
The anionic Re(NO)I52− has been isolated as salts of Cs+, Rb+, and dipyH+. The nonelectrolytic Re(NO)I3L (L stands for 1,10‐phenanthroline and 2,2′‐dipyridyl) and cationic [Re(NO)IL2]PtCl6 have also been prepared. From a solution of Re(NO)(OH)3 in HI, compound of formula Re(H2O)(NO)(OH)I2 has been isolated, pyrolysis of which yielded Re(H2O)0.5(NO)(OH)2I. Measurements of electronic and i.r. spectra and magnetic moments have been carried out. The properties of the iodo derivatives have been compared with those of the corresponding fluoro, chloro and bromo complexes. Copyright © 1981 Verlag GmbH & Co. KGaA, Weinheim
About the journal
JournalZAAC ‐ Journal of Inorganic and General Chemistry
Publisher-
ISSN0044-2313