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General base-tuned unorthodox synthesis of amides and ketoesters with water
S KHAMARUI, R MAITI,
Published in Royal Society of Chemistry
2015
Volume: 51
   
Issue: 2
Pages: 384 - 387
Abstract
We discovered a highly reactive λ3-hypervalent iodane species using an inorganic/organic base for the unorthodox synthesis of amides and ketoesters through grafting terminal alkynes. In contrast to the metal-catalyzed dehydrative approaches the in situ generated nonmetallic reagent efficiently created C-N/C-O and CO bonds with amines/alkynes and water at rt. This journal is © The Royal Society of Chemistry 2015.
About the journal
JournalData powered by TypesetChemical Communications
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN1359-7345