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Free‐electron model for hyperpolarizability of the π‐electron system in benzene
P SEN, S BASU
Published in -
1968
Volume: 2
   
Issue: 5
Pages: 687 - 694
Abstract
The hyperpolarizabilities of benzene have been calculated using a free‐electron model for the π‐electron system. The first hyperpolarizability is identically zero. For the second hyperpolarizability only the components γzzzz; γxxxx; γyyyy; γzzxx; γzzyy; γxxyy are non‐zero. Some of these γ quantities show dispersion near the characteristic absorption band of the benzene molecule. The polarizability α of the π‐electron system also shows similer dispersion. Copyright © 1968 John Wiley & Sons, Inc.
About the journal
JournalInternational Journal of Quantum Chemistry
Publisher-
ISSN0020-7608