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First oxidative synthetic route of a novel, linear mixed valence Co(III){single bond}Co(II){single bond}Co(III) complex with bridging acetate and salen
S CHATTOPADHYAY, G BOCELLI, A MUSATTI,
Published in -
2006
Volume: 9
   
Issue: 10
Pages: 1053 - 1057
Abstract
A linear, trinuclear mixed valence complex [CoII{(μ-L)(μ-OAc)CoIII(NCS)}2] has been prepared and its molecular structure has been elucidated on the basis of X-ray crystallography [H2L = salen = 1,6-bis(2-hydroxyphenyl)-2,5-diazahexa-1,5-diene]. The complex contains a high-spin CoII and two terminal low-spin CoIII, i.e., it is a CoIII(S = 0){single bond}CoII(S = 3/2){single bond}CoIII(S = 0) trimer. © 2006 Elsevier B.V. All rights reserved.
About the journal
JournalInorganic Chemistry Communications
Publisher-
ISSN1387-7003
Open AccessNo