The paper presents the first comprehensive survey of congener profiles of polychlorinated biphenyls (PCBs) in core sediment samples (&lt;63 μm particle size) covering seven sites in Sunderban mangrove Wetland, north-eastern part of the Bay of Bengal. Results pointed out a non-homogenous contamination of the wetland with ∑23PCB values ranging from 0.5 to 26.9 ng g-1 dry weight, reflecting very low to moderate contamination closely in conformity to other Asian coastal environment. The general decreasing order of the dominant congeners to the total load was: CB138 &gt; 153 &gt; 149 &gt; 101, indicating the predominance of hexa-chlorinated congeners. The spatial distribution revealed significant differences in concentration related to local urbanization with industrial and land-based sources. No uniform temporal trend on PCB levels was recorded probably due to particular hydrological characteristics of the wetland and/or non-homogenous inputs from point sources. Strong positive correlations between the seven dominant congeners suggest their common sources and similar environmental behaviors. These results were also used for a risk assessment evaluation in the Sunderban wetland, showing that the present PCB levels were exceeding in few cases the lower limit of sediment quality guidelines of Environmental Protection Agency and Canadian Council of Ministers of the Environment. © Springer Science+Business Media B.V. 2008.

A BINELLI

S K SARKAR

M CHATTERJEE

C RIVA

M PAROLINI

B D BHATTACHARYA

A K BHATTACHARYA

K K SATPATHY

University of Calcutta (informally known as Calcutta University or CU) is a collegiate public state university located in Kolkata, West Bengal, India.&nbsp;Within India it is recognized as a &quot;Five-Star University&quot; and accredited &quot;A&quot; Grade by National Assessment and Accreditation Council.

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The University of Calcutta has secured the Fifth position among the Universities of India in the prestigious &quot;Indian University Ranking 2019&quot; list, released by the NIRF of the Ministry of Human Resource Development, Government of India.

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It was established on 24 January 1857, and was one of the first institutions in Asia to be established as a multidisciplinary and Western-style university. Its alumni and faculty include several heads of state, heads of government, social reformers, prominent artists, only academy award winner and Dirac medal winner in India, many Fellows of the Royal Society and five Nobel laureates as of 2019 which is highest in South Asia.

University Of Calcutta

Environmental Monitoring and Assessment

This study investigated polycyclic aromatic hydrocarbons (PAHs) and organochlorine compounds such as polychlorinated biphenyls (PCBs) and DDT-related pesticides in surface sediments of Hooghly estuary and the Sundarban mangrove wetlands. Concentrations of ∑17PAH, ∑182PCB and ∑6DDT ranged from 15.4 to 1731, not detected (nd) to 13.5 and nd to 8.97 ng g−1 dry weight, respectively. Low levels of PCBs and low to moderate concentrations of DDTs and PAHs reflected recent development in West Bengal, which was dominated by agriculture and multifarious industries in the past. Diagnostic ratios suggested that major sources of PAHs are combustion processes, DDTs are input by agriculture, antifouling paints and public health campaigns, and organochlorines are predominantly from industrial origin. Heavier PCB congeners suggest local sources and short-range transport of such chemicals. Decision makers may use these findings for managing the Hooghly River watershed in order to promote a sustainable development on the eastern coast of India. © 2019 Elsevier Ltd

Marine Pollution Bulletin

Distribution and sources of organic contaminants in surface sediments of Hooghly river estuary and Sundarban mangrove, eastern coast of India

The aim of this paper was to obtain the first screening ecotoxicological risk evaluation in the Sunderban wetlands, the largest prograding delta in the estuarine phase of the River Ganges. The characterization of exposure was conducted by means of an extensive survey of several persistent organic pollutants (PAHs, PCBs, DDTs, PBDEs, HCHs, HCB) measured in seven core sediments from the Sunderban wetlands, obtaining a dataset with more than 2200 analyses. The pollutant effects were assessed by the use of three different sediment quality guidelines (SQGs) previously developed in the literature to evaluate toxicity induced in sediment-dwelling organisms. The three different approaches chosen for risk assessment of the Sunderban were the consensus SQGs obtained by TEC (threshold effect concentration), PEC (probable effect concentration) and EEC (extreme effect concentration), the threshold/probable effect level (TEL/PEL) approach and, finally, the ERL-ERM guidelines, including the m-ERM-Q (mean ERM quotient). The evaluation of the toxicity induced by a mixture of the target pollutants indicated the importance of γ-HCH contamination in the Sunderban sediments despite the very low concentrations measured in core sediments. A different sensitivity for toxicity assessment due to quality guidelines was obtained, as the consensus SQGs based on TEC were less conservative and protective than the TEL and ERL approaches, while the use of m-ERM-Q seems to be the most powerful tool to predict the toxicity related to a contaminant mixture. © 2008 Elsevier Ltd. All rights reserved.

Chemosphere

A comparison of sediment quality guidelines for toxicity assessment in the Sunderban wetlands (Bay of Bengal, India)

This paper presents the first comprehensive report of the organochlorine pesticide residues (OCs) such as hexachlorocyclohexane isomers (HCHs), dichlorodiphenyltrichloroethane and its six metabolites (DDTs), and hexachlorobenzene (HCB) in core sediments (&lt;63-μm particle size) from the Indian Sunderban wetland. The pooled mean values of the mass fraction of ∑HCHs, HCB, and ∑DDTs in the sediments were 0.05-12, 0.05-1.4, and 0.05-11.5 ng g-1 dry weight, respectively. The vertical distribution of pesticides reveals an erratic pattern. The concentration of four isomers of HCHs reveals a heterogenic distribution where γ-HCH (lindane) and β-HCH shared the dominant part. The mass fraction of HCB did not show any sharp spatial variation. The prevailing sequence of DDT metabolites indicates an active degradation of the parent compound in the sediments and/or inputs of already degraded pp'DDT to the region. Peak concentrations of HCH isomers and DDT metabolites have the potential to induce ecotoxicological impact as per the sediment quality guidelines. © 2008 Springer Science+Business Media, LLC.

Archives of Environmental Contamination and Toxicology

Organochlorine pesticide residues in sediment cores of Sunderban wetland, northeastern part of bay of Bengal, India, and their ecotoxicological significance

The paper presents the first document regarding concentration, distribution and possible sources of selected trace elements (Cu, Fe, Mn, Zn, Cr, Co, Ni, Pb, Al, B and Ba) in core sediments (&lt; 63 μ particle size) from the lower stretch of Hugli (Ganges) estuary, northeast coast of Bay of Bengal by ICP-AES and EDXRF to evaluate geochemical processes influencing their distribution and possible environmental consequences. The levels of elements showed a wide range of variations in different core depths, in upper and lower intertidal zones as well as among three sampling stations. The most interesting feature of the study is the downward increase of concentrations of majority of the elements reaching overall maximum values at a depth of 20-28 cm in upper littoral zone of the site located in the extreme downstream stretch of the estuary. Values of organic carbon showed very strong positive correlations with most of the elements as revealed by correlation matrix (r) values. The interelemental relationship revealed the identical behavior of element during its transport in the estuarine environment. The overall variation in concentration can be attributed to differential discharge of untreated effluents originating from industrial, agricultural, and aquacultural sources as well as from domestic sewage along with the fishing and boating activities. The resulting compositional dataset was tested by principal component analyses and cluster analyses. Pollution load index (PLI) and index of Geoaccumulation (Igeo) revealed overall low values but the enrichment factors (EFs) for Pb were typically high for all the stations. The mean concentrations of Zn and to some extent Cu exceeded the Effects Range-Low (ER-L) values in the majority of the cases indicating that there may be some ecotoxicological risk to organisms living in sediments. The concentration of the trace elements reported in this work is useful as baselines for comparison in future sediment quality studies. © 2006 Elsevier Ltd. All rights reserved.

Environment International

Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance

The lower tidal stretch of the river Ganges, known as Hugli (ca. 280 km), flows southward before entering the Bay of Bengal forming a vast mangrove-enriched estuarine delta called Sunderbans. Hugli estuary is a typical example of tide-dominated sink for contaminants from multifarious sources. This major important river is subjected to anthropogenic stress due to the socio-economic importance of these areas based on growth of industry, agriculture, aquaculture, port activities, fishing and tourism. The living resources have been degraded recently due to increases in population pressure, pollution and natural resource consumption to the extent of overexploitation. The present paper critically examines the physicochemical characteristics and level of dissolved heavy metals at three ecologically distinct zones along the course of the river - Babughat located in the eastern part of the metropolitan megacity Calcutta (140 km upstream from seaface), Diamond Harbor (70 km upstream from sea face) and Gangasagar positioned at the mouth of the Ganges estuary. Physicochemical characteristics of this partially mixed estuary are largely influenced by the interaction of seawater and discharge of riverine freshwater, annual precipitation and surface runoff. The levels of salinity, total dissolved solids, hardness and conductivity showed an increasing downward trend. Marked increase in biochemical oxygen demand (BOD) values (2.20-5.95 mg/l) was recorded in Babughat whereas correspondingly low values (0.75-2.82 mg/l) were noticed at Gangasagar. This can be attributed mainly due to huge organic load of untreated sewage from the twin city Howrah and Calcutta situated in the east and west of the river. Spatiotemporal distribution of heavy metals reveals a wide range of variations reflecting input of huge anthropogenic inputs associated with a number of physical and chemical processes. Levels of metals registered a seasonal pattern, with an increase during late monsoon months (September-October), a period characterized by low salinity and relatively low pH of the water. Elevated levels of dissolved Hg and Pb were also recorded in Babughat, with values ranging from 0.16 to 0.95 μg/ml and 0.017 to 0.076 μg/ml, respectively, this high values for Hg can be attributed to the discharge from pulp and paper manufacturing units and to atmospheric input and runoff of automobile emission for Pb. It was revealed that the socio-economic development of Calcutta, the most potential economic zone in India situated on the east bank of Hugli river, has had a significant impact on the water quality of this major river. The deterioration of water quality is directly related to nonfunctioning and malfunctioning of wastewater treatment plants and lack of environmental planning and coordination. To restore the ecological stability and economic vitality of this river, the following measures have been suggested: (i) strong vigilance programme is to be undertaken towards installation and maintenance of the wastewater treatment plants to check the flow of persistent contaminants in the river water and (ii) execution of legislation and mass awareness programmes are to be enacted to restore the sound health of the river. The authors urge that environmental education should be used as an effective tool for water resource management dealing with intricate and complex problems in the interaction between nature, technology and human beings. © 2006 Elsevier Ltd. All rights reserved.

Journal of Cleaner Production

Water quality management in the lower stretch of the river Ganges, east coast of India: an approach through environmental education

The paper presents the first comprehensive survey of congener profiles (12 congeners) of polybrominated diphenyl ethers (PBDEs) in core sediment samples (&lt;63 μm) covering seven sites in Sundarban mangrove wetland (India). Gas-chromatographic analyses were carried out in GC-Ms/Ms for tri- to hepta- brominated congeners. Results pointed out a non-homogenous contamination of the wetland with ∑12 PBDE values ranging from 0.08 to 29.03 ng g-1, reflecting moderate to low contamination closely in conformity to other Asian aquatic environments. The general order of decreasing congener contribution to the total load was: BDE 47 &gt; 99 &gt; 100 &gt; 154, similar to the distribution pattern worldwide. Although tetrabromodiphenyl ether BDE 47 was found in all samples followed by hexabromodiphenyl ether BDE-154, they were not necessarily the dominant congeners. No uniform temporal trend on PBDE levels was recorded probably due to particular hydrological characteristics of the wetland and/on non-homologous inputs from point sources (untreated municipal wastewater and local industries, electronic wastes from the dump sites, etc.) of these compounds. Because of the propensity of PBDEs to accumulate in various compartments of wildlife and human food webs, evaluation of biological tissues should be undertaken as a high priority. © 2007 Elsevier Ltd. All rights reserved.

Concentration of polybrominated diphenyl ethers (PBDEs) in sediment cores of Sundarban mangrove wetland, northeastern part of Bay of Bengal (India)

Detailed analyses of persistent organic pollutants (POPs) such as hexachlorocyclohexane (HCH) isomers (HCHs), dichlorodiphenyltrichloro ethane (DDT) and its metabolites (DDTs), hexachlorobenzene (HCB) and congeners of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in surface sediments from the coastal estuarine environment of West Bengal, northeast India allowed the evaluation of the contamination status, distribution and possible pollution sources. HCH, DDT, HCB, PCB and PAH were identified compounds in all the samples, whereas the concentrations of chlorinated pesticides (trans-eptachlorepoxide, dieldrin, endrin, metaoxychlor and mirex) were below the detection limits and were not of great concern. The pesticides did demonstrate markedly different distributions reflecting different agricultural and domestic usage in the region. The range of concentrations of HCH, HCB, DDT and PCBs in the sediments were 0.11-0.40, &lt;0.05-0.98, 0.18-1.93 and 0.18-2.33 ng/g dry wt, respectively. Overall elevated levels of HCB, DDT and PCB were recorded at Babughat, a very closely located site of the metropolitan megacity Calcutta. Fluoranthene (flu) and pyrene (py), the dominant 4-ring PAHs, also showed an abrupt elevated concentrations at Babughat with values of 214 and 144 ng/g dry wt, respectively. Among the isomers and metabolites of HCH, DDT and PCB, α-HCH, pp′-DDT and PCB 101, PCB 118, PCB153 and PCB 138 were found to be dominant. High ratios of metabolites of DDT to ΣDDTs reveal recent use of DDT in this coastal environment. Fluoranthene, pyrene, 1,2-benzo(a)anthracene and chrysene formed the dominant congeners out of 19 identified PAHs. The sources of contamination are closely related to human activities such as domestic and industrial discharge, automobile exhausts, street runoff, slum sewage, agricultural chemicals and soil erosion due to deforestation as well as atmospheric transport. This study is compared to other coastal and estuarine environments in India and abroad. The baseline data can be used for regular ecological monitoring, considering the industrial and agricultural growth around this important estuarine ecosystem. © 2004 Elsevier Ltd. All rights reserved.

Journal	Environmental Monitoring and Assessment
Publisher	-
ISSN	0167-6369