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AuCl3 catalyzed [3 + 2 + 1] cycloaddition: First use of aldehyde as a carbon monoxide-like one carbon synthon for triple C-C coupling
K S GAYEN,
Published in -
2014
Volume: 4
   
Issue: 20
Pages: 10204 - 10207
Abstract
A new [3 + 2 + 1] cycloaddition strategy is demonstrated using an aldehyde, an aldimine of a glycine ester and a terminal triple bond with AuCl3 catalyst. Aldehyde is exploited as the first alternative to the crucial partner CO for triple C-C coupled annulation for the synthesis of novel fused-tricyclic heterocycles. © 2014 The Royal Society of Chemistry.
About the journal
JournalRSC Advances
Publisher-
ISSN2046-2069